Premium
Synthetic Routes for Heteroatom‐Containing Alkylated/Arylated Polycyclic Aromatic Hydrocarbons
Author(s) -
Shi Qinqin,
Shi Xiaosong,
Feng Changfu,
Wu Yishi,
Zheng Nan,
Liu Jie,
Wu Xiaoxi,
Chen Hao,
Peng Aidong,
Li Jianfeng,
Jiang Lang,
Fu Hongbing,
Xie Zengqi,
Marder Seth R.,
Blakey Simon B.,
Huang Hui
Publication year - 2021
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.202014108
Subject(s) - heteroatom , chemistry , alkyl , single crystal , aryl , alkylation , cyclic voltammetry , organic chemistry , crystallography , electrode , electrochemistry , catalysis
Synthetic routes for heteroatom‐containing polycyclic aromatic hydrocarbons (H‐PAHs) with alkyl and aryl substitution are demonstrated. Three H‐PAHs, including heteroatom‐containing rubicenes (H‐rubicenes), angular‐benzothiophenes (ABTs), and indenothiophene (IDTs) were successfully synthesized by two key steps, including polysubstituted olefin formation and cyclization. Specifically, ABT and H‐rubicenes were comprehensively investigated by single‐crystal X‐ray diffraction, NMR spectroscopy, UV‐vis absorption, cyclic voltammetry, transient absorption, and single‐crystal OFET measurements.