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Inside Back Cover: Sequential Chiral Induction and Regulator‐Assisted Chiral Memory of Pillar[5]arenes (Angew. Chem. Int. Ed. 46/2020)
Author(s) -
Fa Shixin,
Egami Kouichi,
Adachi Keisuke,
Kato Kenichi,
Ogoshi Tomoki
Publication year - 2020
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.202013285
Subject(s) - regulator , chirality (physics) , pillar , planar chirality , planar , chemistry , stereochemistry , materials science , nanotechnology , enantioselective synthesis , physics , computer science , chiral anomaly , engineering , organic chemistry , nambu–jona lasinio model , quantum mechanics , biochemistry , structural engineering , gene , catalysis , computer graphics (images) , fermion
Chirality transfer is widely observed in life processes. In their Communication on page 20353, T. Ogoshi and co‐workers introduce a new non‐direct chiral transfer system, in which the chiral induction and memory processes occur within a single system via the synergistic interactions of a chiral regulator and inducer. The planar chirality of an acceptor is induced and memorized by a chiral inducer with precise control by a regulator. The memorization of the planar chirality of pillar[5]arenes by the regulator (net) is illustrated.