Diels–Alder Conversion of Acrylic Acid and 2,5‐Dimethylfuran to  para ‐Xylene Over Heterogeneous Bi‐BTC Metal‐Organic Framework Catalysts Under Mild Conditions | Zendy

Yeh JyunYi | Zendy; Chen Season S. | Zendy; Li ShihCheng | Zendy; Chen Celine H. | Zendy; Shishido Tetsuya | Zendy; Tsang Daniel C. W. | Zendy; Yamauchi Yusuke | Zendy; Li YiPei | Zendy; Wu Kevin C.W. | Zendy

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Diels–Alder Conversion of Acrylic Acid and 2,5‐Dimethylfuran to para ‐Xylene Over Heterogeneous Bi‐BTC Metal‐Organic Framework Catalysts Under Mild Conditions

Author(s) -

Yeh JyunYi,

Chen Season S.,

Li ShihCheng,

Chen Celine H.,

Shishido Tetsuya,

Tsang Daniel C. W.,

Yamauchi Yusuke,

Li YiPei,

Wu Kevin C.W.

Publication year - 2021

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.202013061

Subject(s) - furan , acrylic acid , metal organic framework , yield (engineering) , catalysis , chemistry , raw material , organic chemistry , xylene , o xylene , metal , materials science , polymer , copolymer , composite material , benzene , adsorption

The heterogeneous metal‐organic framework Bi‐BTC successfully catalyzed the synthesis of para ‐xylene from bio‐based 2,5‐dimethylfuran and acrylic acid in a promising yield (92 %), under relatively mild conditions (160 °C, 10 bar), and with a low reaction‐energy barrier (47.3 kJ mol −1 ). The proposed reaction strategy also demonstrates a remarkable versatility for furan derivatives such as furan and 2‐methylfuran.

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