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Geometry‐Directed Self‐Assembly of Polymeric Molecular Frameworks
Author(s) -
Yan XiaoYun,
Guo QingYun,
Lin Zhiwei,
Liu XianYou,
Yuan Jun,
Wang Jing,
Wang Haomin,
Liu Yuchu,
Su Zebin,
Liu Tong,
Huang Jiahao,
Zhang Ruimeng,
Wang Yicong,
Huang Mingjun,
Zhang Wei,
Cheng Stephen Z. D.
Publication year - 2021
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.202012117
Subject(s) - polymer , nanotechnology , materials science , construct (python library) , self assembly , amphiphile , work (physics) , thermal stability , scalability , computer science , copolymer , chemical engineering , mechanical engineering , engineering , composite material , database , programming language
Despite the significant advances in creating assembled structures from polymers, engineering the assembly of polymeric materials into framework structures remains an outstanding challenge. In this work, we present a facile strategy to construct polymeric molecular frameworks through the assembly of T‐shape polymer‐rod‐sphere amphiphiles in the bulk state. Various frameworks are yielded as a result of delicate interplays among three components of the T‐shape amphiphiles. The internal structure of frameworks was revealed by combining experimental investigations and computational simulations. The frameworks display good solution‐processability, thermal stability, and uniform pore‐forming capability, which endow the resultant frameworks with great potential in scalable fabrications.