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A Surface‐Strained and Geometry‐Tailored Nanoreactor that Promotes Ammonia Electrosynthesis
Author(s) -
Li Panpan,
Jin Zhaoyu,
Fang Zhiwei,
Yu Guihua
Publication year - 2020
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.202011596
Subject(s) - nanoreactor , electrosynthesis , ammonia production , catalysis , materials science , chemical engineering , ammonia , faraday efficiency , selectivity , nitrogen , aqueous solution , nanotechnology , electrochemistry , chemistry , organic chemistry , electrode , engineering
A surface‐strained and geometry‐optimized TiO 2 nanoreactor enhances the performance of electrocatalytic nitrogen fixation. The nanotubular confinement allows spatial regulation of the mass transport of nitrogen during the NRR process and offers an enlarged surface area, thus boosting the ammonia production with high selectivity. Both experimental and theoretical evidence support strained Ti 3+ sites, demonstrating a more favorable pathway for the N 2 activation and selective NH 3 production with a faster kinetic rate than the pristine TiO 2 . The TiO 2 ‐based nanoreactor with surface and bulk structure tailoring delivered an NH 3 yield rate up to 5.50 μg h −1 cm −2 (16.67 μg h −1 mg cat −1 ) and high faradaic efficiency of 26 % under ambient aqueous conditions. Our findings highlight the concept of lattice strain and geometry modified nanoreactors, which will have broad implications in the renewable energy catalysis and electrosynthesis of valuable products.