Premium
Potential‐Dependent Morphology of Copper Catalysts During CO 2 Electroreduction Revealed by In Situ Atomic Force Microscopy
Author(s) -
Simon Georg H.,
Kley Christopher S.,
Roldan Cuenya Beatriz
Publication year - 2021
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.202010449
Subject(s) - electrochemistry , copper , catalysis , electrolyte , atomic units , nanoscopic scale , atomic force microscopy , morphology (biology) , materials science , in situ , micrometer , adsorption , cathodic protection , chemical physics , nanotechnology , characterization (materials science) , chemical engineering , single displacement reaction , chemistry , inorganic chemistry , electrode , metallurgy , biochemistry , physics , organic chemistry , quantum mechanics , engineering , biology , optics , genetics
Electrochemical AFM is a powerful tool for the real‐space characterization of catalysts under realistic electrochemical CO 2 reduction (CO 2 RR) conditions. The evolution of structural features ranging from the micrometer to the atomic scale could be resolved during CO 2 RR. Using Cu(100) as model surface, distinct nanoscale surface morphologies and their potential‐dependent transformations from granular to smoothly curved mound‐pit surfaces or structures with rectangular terraces are revealed during CO 2 RR in 0.1 m KHCO 3 . The density of undercoordinated copper sites during CO 2 RR is shown to increase with decreasing potential. In situ atomic‐scale imaging reveals specific adsorption occurring at distinct cathodic potentials impacting the observed catalyst structure. These results show the complex interrelation of the morphology, structure, defect density, applied potential, and electrolyte in copper CO 2 RR catalysts.