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Rational Assembly of Metallophilic Gold(I)–Lead(II) and Gold(I)–Gold(I) Puzzle Pieces
Author(s) -
LópezdeLuzuriaga José M.,
Monge Miguel,
Moreno Sonia,
Olmos M. Elena,
RodríguezCastillo María
Publication year - 2021
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.202010095
Subject(s) - stacking , chemistry , terpyridine , crystallography , stereochemistry , nanotechnology , materials science , metal , organic chemistry
The assembly of two different building blocks, [{Au(C 6 F 5 ) 2 }{PbCl(terpy)}] (terpy=2,2′:6′:2′′‐terpyridine) and [{Au(C 6 F 5 ) 2 } 2 {Pb(terpy)}] n , acting as terminal or central pieces, respectively, gives rise to a decanuclear complex built via metallophilic and π‐stacking interactions in which the number of Au I ⋅⋅⋅Au I and Au I ⋅⋅⋅Pb II contacts is finely controlled.