Rational Assembly of Metallophilic Gold(I)–Lead(II) and Gold(I)–Gold(I) Puzzle Pieces | Zendy

LópezdeLuzuriaga José M. | Zendy; Monge Miguel | Zendy; Moreno Sonia | Zendy; Olmos M. Elena | Zendy; RodríguezCastillo María | Zendy

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Rational Assembly of Metallophilic Gold(I)–Lead(II) and Gold(I)–Gold(I) Puzzle Pieces

Author(s) -

LópezdeLuzuriaga José M.,

Monge Miguel,

Moreno Sonia,

Olmos M. Elena,

RodríguezCastillo María

Publication year - 2021

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.202010095

Subject(s) - stacking , chemistry , terpyridine , crystallography , stereochemistry , nanotechnology , materials science , metal , organic chemistry

The assembly of two different building blocks, [{Au(C 6 F 5 ) 2 }{PbCl(terpy)}] (terpy=2,2′:6′:2′′‐terpyridine) and [{Au(C 6 F 5 ) 2 } 2 {Pb(terpy)}] n , acting as terminal or central pieces, respectively, gives rise to a decanuclear complex built via metallophilic and π‐stacking interactions in which the number of Au I ⋅⋅⋅Au I and Au I ⋅⋅⋅Pb II contacts is finely controlled.

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