A Bis‐Acridinium Macrocycle as Multi‐Responsive Receptor and Selective Phase‐Transfer Agent of Perylene | Zendy

Hu Johnny | Zendy; Ward Jas S. | Zendy; Chaumont Alain | Zendy; Rissanen Kari | Zendy; Vincent JeanMarc | Zendy; Heitz Valérie | Zendy; Jacquot de Rouville HenriPierre | Zendy

AI Assistant Blog Pricing

Home ZAIA Blog

Premium

A Bis‐Acridinium Macrocycle as Multi‐Responsive Receptor and Selective Phase‐Transfer Agent of Perylene

Author(s) -

Hu Johnny,

Ward Jas S.,

Chaumont Alain,

Rissanen Kari,

Vincent JeanMarc,

Heitz Valérie,

Jacquot de Rouville HenriPierre

Publication year - 2020

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.202009212

Subject(s) - perylene , chemistry , cyclophane , hydroxide , redox , hydrocarbon , photochemistry , phase (matter) , aromatic hydrocarbon , polycyclic aromatic hydrocarbon , molecule , combinatorial chemistry , organic chemistry

A bis‐acridinium cyclophane incorporating switchable acridinium moieties linked by a 3,5‐dipyridylanisole spacer was studied as a multi‐responsive host for polycyclic aromatic hydrocarbon guests. Complexation of perylene was shown to be the most effective and was characterized in particular by a charge‐transfer band as signal output. Effective catch and release of the guest was triggered by both chemical (proton/hydroxide) and redox stimuli. Moreover, the dicationic host was also easily switched between organic and perfluorocarbon phases for applications related to the enrichment of perylene from a mixture of polycyclic aromatic hydrocarbons.

This content is not available in your region!

Continue researching here.

Having issues? You can contact us here

Accelerating Research