Direct and Selective Synthesis of Adipic and Other Dicarboxylic Acids by Palladium‐Catalyzed Carbonylation of Allylic Alcohols | Zendy

Yang Ji | Zendy; Liu Jiawang | Zendy; Ge Yao | Zendy; Huang Weiheng | Zendy; Neumann Helfried | Zendy; Jackstell Ralf | Zendy; Beller Matthias | Zendy

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Direct and Selective Synthesis of Adipic and Other Dicarboxylic Acids by Palladium‐Catalyzed Carbonylation of Allylic Alcohols

Author(s) -

Yang Ji,

Liu Jiawang,

Ge Yao,

Huang Weiheng,

Neumann Helfried,

Jackstell Ralf,

Beller Matthias

Publication year - 2020

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.202008916

Subject(s) - carbonylation , palladium , chemistry , allylic rearrangement , catalysis , adipic acid , selectivity , ligand (biochemistry) , alcohol , organic chemistry , dicarboxylic acid , carbon monoxide , biochemistry , receptor

A general and direct synthesis of dicarboxylic acids including industrially important adipic acid by palladium‐catalyzed dicarbonylation of allylic alcohol is reported. Specifically, the combination of PdCl 2 and a bisphosphine ligand (HeMaRaphos) promotes two different carbonylation reactions with high activity and excellent selectivity.

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