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Direct and Selective Synthesis of Adipic and Other Dicarboxylic Acids by Palladium‐Catalyzed Carbonylation of Allylic Alcohols
Author(s) -
Yang Ji,
Liu Jiawang,
Ge Yao,
Huang Weiheng,
Neumann Helfried,
Jackstell Ralf,
Beller Matthias
Publication year - 2020
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.202008916
Subject(s) - carbonylation , palladium , allylic rearrangement , catalysis , chemistry , selectivity , adipic acid , alcohol , ligand (biochemistry) , organic chemistry , carbon monoxide , receptor , biochemistry
Abstract A general and direct synthesis of dicarboxylic acids including industrially important adipic acid by palladium‐catalyzed dicarbonylation of allylic alcohol is reported. Specifically, the combination of PdCl 2 and a bisphosphine ligand (HeMaRaphos) promotes two different carbonylation reactions with high activity and excellent selectivity.