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LaOCl‐Coupled Polymeric Carbon Nitride for Overall Water Splitting through a One‐Photon Excitation Pathway
Author(s) -
Lin Yuan,
Su Wenyue,
Wang Xuxu,
Fu Xianzhi,
Wang Xinchen
Publication year - 2020
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.202008397
Subject(s) - photocatalysis , water splitting , carbon nitride , semiconductor , band gap , artificial photosynthesis , materials science , nitride , excitation , optoelectronics , carbon fibers , wide bandgap semiconductor , photocatalytic water splitting , photochemistry , composite number , nanotechnology , chemistry , catalysis , composite material , layer (electronics) , physics , organic chemistry , quantum mechanics
It is a challenge to explore photocatalytic materials for sunlight‐driven water splitting owing to the limited choice of a single semiconductor with suitable band energy levels but with a minimized band gap for light harvesting. Here, we report a one‐photon excitation pathway by coupling polymeric carbon nitride (PCN) semiconductor with LaOCl to achieve overall water splitting. This artificial photosynthesis composite catalyzes the decomposition of H 2 O into H 2 and O 2 , with evolution rates of 22.3 and 10.7 μmol h −1 , respectively. The high photocatalytic performance of PCN/LaOCl can be ascribed to the simultaneously accomplished reduction and oxidation of water on LaOCl and PCN domains, respectively, as well as the fast charge separation and migration induced by the interfacial electric field related to LaOCl modification. This study provides new insights on the development of composite photocatalysts for pure water splitting based on polymer‐based materials via charge modulation.