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Inside Cover: A Sodalite‐Type Silver Orthophosphate Cluster in a Globular Silver Nanocluster (Angew. Chem. Int. Ed. 31/2020)
Author(s) -
Deng Chenglong,
Sun Cunfa,
Wang Zhi,
Tao Yunwen,
Chen Yilin,
Lin Jinqing,
Luo Genggeng,
Lin Bizhou,
Sun Di,
Zheng Lansun
Publication year - 2020
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Reports
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.202007212
Subject(s) - sodalite , globular cluster , cover (algebra) , materials science , crystallography , cluster (spacecraft) , nanotechnology , type (biology) , octahedron , chemistry , physics , computer science , geology , astrophysics , crystal structure , engineering , zeolite , mechanical engineering , galaxy , programming language , catalysis , paleontology , biochemistry
A silver orthophosphate cluster (SOC) can be stabilized in the cavity of a giant silver nanocluster. In their Communication on page 12659, G. Luo, D. Sun, and co‐workers present a multi‐shell 102‐silver nanocluster in which a rare rhombicosidodecahedral 60‐silver nanocluster accommodates an unprecedented sodalite‐type SOC {(Ag 3 PO 4 ) 8 } concomitantly encapsulating an octahedral Ag 6 core. This study is the first presentation of the SOC concept.