Premium
[BO 2 ] − as a Synthon for the Generation of Boron‐Centered Carbamate and Carboxylate Isosteres
Author(s) -
Pécharman AnneFrédérique,
Hill Michael S.,
McMullin Claire L.,
Mahon Mary F.
Publication year - 2020
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.202005674
Subject(s) - synthon , carboxylate , boron , carbamate , chemistry , stereochemistry , medicinal chemistry , organic chemistry
Abstract Oxoborane carbamate and carboxylate analogues result from the in situ trapping of [BO 2 ] − produced by elimination of 2,3‐dimethyl‐2‐butene from a pinacolatoboryl anion.