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Mixed Phosphatetrahedranes
Author(s) -
Jupp Andrew R.,
Slootweg J. Chris
Publication year - 2020
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.202004514
Subject(s) - biology
P‐yramids : Tetrahedranes are highly strained molecules, and the all‐carbon (C t Bu) 4 and all‐phosphorus species P 4 have been known for decades and centuries, respectively. Despite this, the mixed P/C tetrahedranes were unknown until recently when the syntheses of the phosphatetrahedranes P(C t Bu) 3 and P 2 (C t Bu) 2 were reported by the research groups of Cummins and Wolf.