Premium
A Cation and Anion Dual Doping Strategy for the Elevation of Titanium Redox Potential for High‐Power Sodium‐Ion Batteries
Author(s) -
Chen Mingzhe,
Xiao Jin,
Hua Weibo,
Hu Zhe,
Wang Wanlin,
Gu Qinfen,
Tang Yuxin,
Chou ShuLei,
Liu HuaKun,
Dou ShiXue
Publication year - 2020
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.202003275
Subject(s) - redox , cathode , ion , sodium , electrochemistry , materials science , doping , titanium , phase (matter) , diffusion , thermal stability , chemistry , inorganic chemistry , electrode , thermodynamics , optoelectronics , metallurgy , organic chemistry , physics
Abstract Titanium‐based polyanions have been intensively investigated for sodium‐ion batteries owing to their superior structural stability and thermal safety. However, their low working potential hindered further applications. Now, a cation and anion dual doping strategy is used to boost the redox potential of Ti‐based cathodes of Na 3 Ti 0.5 V 0.5 (PO 3 ) 3 N as a new cathode material for sodium ion batteries. Both the Ti 3+ /Ti 4+ and V 3+ /V 4+ redox couples are reversibly accessed, leading to two distinctive voltage platforms at ca. 3.3 V and ca. 3.8 V, respectively. The remarkably improved cycling stability (86.3 %, 3000 cycles) can be ascribed to the near‐zero volume strain in this unusual cubic symmetry, which has been demonstrated by in situ synchrotron‐based X‐ray diffraction. First‐principles calculations reveal its well‐interconnected 3D Na diffusion pathways with low energy barriers, and the two‐sodium‐extracted intermediate NaTi 0.5 V 0.5 (PO 3 ) 3 N is also a stable phase according to formation energy calculations.