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Trapping of Difluorocarbene by Frustrated Lewis Pairs
Author(s) -
Smirnov Vladimir O.,
Volodin Alexander D.,
Korlyukov Alexander A.,
Dilman Alexander D.
Publication year - 2020
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.202001354
Subject(s) - difluorocarbene , frustrated lewis pair , trapping , lewis acids and bases , physics , chemistry , medicinal chemistry , catalysis , organic chemistry , geography , forestry
Frustrated Lewis pairs consisting of diphenylphosphino and boryl groups located at the ortho ‐position can trap difluorocarbene affording stable zwitterionic adducts. The reaction can be reversed to release difluorocarbene at elevated temperatures.