Electrochemical Synthesis of Thienoacene Derivatives: Transition‐Metal‐Free Dehydrogenative C−S Coupling Promoted by a Halogen Mediator | Zendy

Mitsudo Koichi | Zendy; Matsuo Ren | Zendy; Yonezawa Toki | Zendy; Inoue Haruka | Zendy; Mandai Hiroki | Zendy; Suga Seiji | Zendy

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Electrochemical Synthesis of Thienoacene Derivatives: Transition‐Metal‐Free Dehydrogenative C−S Coupling Promoted by a Halogen Mediator

Author(s) -

Mitsudo Koichi,

Matsuo Ren,

Yonezawa Toki,

Inoue Haruka,

Mandai Hiroki,

Suga Seiji

Publication year - 2020

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.202001149

Subject(s) - halogen , electrochemistry , transition metal , chemistry , coupling (piping) , mediator , materials science , organic chemistry , catalysis , metallurgy , electrode , medicine , alkyl

The first electrochemical dehydrogenative C−S bond formation leading to thienoacene derivatives is described. Several thienoacene derivatives were synthesized by dehydrogenative C−H/S−H coupling. The addition of n Bu 4 NBr, which catalytically promoted the reaction as a halogen mediator, was essential.

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