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Light‐Driven Crawling of Molecular Crystals by Phase‐Dependent Transient Elastic Lattice Deformation
Author(s) -
Gong Yanjun,
Guo Yongxian,
Ge Fayuan,
Xiong Wei,
Su Jie,
Sun Yang,
Zhang Chuang,
Cao AnMin,
Zhang Yifan,
Zhao Jincai,
Che Yanke
Publication year - 2020
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.202000570
Subject(s) - materials science , transient (computer programming) , crawling , deformation (meteorology) , lattice (music) , mechanics , condensed matter physics , composite material , optics , physics , computer science , acoustics , medicine , anatomy , operating system
The light‐driven crawling of a molecular crystal that can form three phases, (α, β, and γ) is presented. Laser irradiation of the molecular crystal can generate phase‐dependent transient elastic lattice deformation. The resulting elastic lattice deformation that follows scanning irradiation of a laser can actuate the different phases of molecular crystal to move with different velocity and direction. Because the γ phase has a large Young's modulus (ca. 26 GPa), a force of 0.1 μN can be generated under one laser spot. The generated force is sufficient to actuate the γ‐formed molecular crystals in a wide dimensional range to move longitudinally at a velocity of about 60 μm min −1 , which is two orders of magnitude faster than the α and β phases.