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Frontispiece: Reverse Arene Sandwich Structures Based upon π‐Hole⋅⋅⋅[M II ] (d 8 M=Pt, Pd) Interactions, where Positively Charged Metal Centers Play the Role of a Nucleophile
Author(s) -
Rozhkov Anton V.,
Krykova Mariya A.,
Ivanov Daniil M.,
Novikov Alexander S.,
Sinelshchikova Anna A.,
Volostnykh Marina V.,
Konovalov Mikhail A.,
Grigoriev Mikhail S.,
Gorbunova Yulia G.,
Kukushkin Vadim Yu.
Publication year - 2019
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Reports
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.201981361
Subject(s) - metal , planar , nucleophile , charge (physics) , square (algebra) , crystallography , chemistry , materials science , physics , catalysis , organic chemistry , geometry , computer science , computer graphics (images) , mathematics , quantum mechanics
Reverse Sandwich Compounds In their Communication on page 4164 ff., V. Y. Kukushkin et al. show how square‐planar Pt II and Pd II systems give reverse sandwich structures in which the charge distribution at the metal and the arenes is opposite to that of classic sandwich species.