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Designing a 0D/2D S‐Scheme Heterojunction over Polymeric Carbon Nitride for Visible‐Light Photocatalytic Inactivation of Bacteria
Author(s) -
Xia Pengfei,
Cao Shaowen,
Zhu Bicheng,
Liu Mingjin,
Shi Miusi,
Yu Jiaguo,
Zhang Yufeng
Publication year - 2020
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.201916012
Subject(s) - heterojunction , photocatalysis , carbon nitride , x ray photoelectron spectroscopy , visible spectrum , materials science , optoelectronics , electron paramagnetic resonance , irradiation , photochemistry , quantum dot , semiconductor , graphitic carbon nitride , carbon fibers , chemistry , chemical engineering , catalysis , physics , organic chemistry , nuclear magnetic resonance , composite number , nuclear physics , engineering , composite material
Constructing heterojunctions between two semiconductors with matched band structure is an effective strategy to acquire high‐efficiency photocatalysts. The S‐scheme heterojunction system has shown great potential in facilitating separation and transfer of photogenerated carriers, as well as acquiring strong photoredox ability. Herein, a 0D/2D S‐Scheme heterojunction material involving CeO 2 quantum dots and polymeric carbon nitride (CeO 2 /PCN) is designed and constructed by in situ wet chemistry with subsequent heat treatment. This S‐scheme heterojunction material shows high‐efficiency photocatalytic sterilization rate (88.1 %) towards Staphylococcus aureus (S. aureus) under visible‐light irradiation ( λ ≥420 nm), which is 2.7 and 8.2 times that of pure CeO 2 (32.2 %) and PCN (10.7 %), respectively. Strong evidence of S‐scheme charge transfer path is verified by theoretical calculations, in situ irradiated X‐ray photoelectron spectroscopy, and electron paramagnetic resonance.