A Neutral and Aromatic Boron‐Rich Inorganic Benzene | Zendy

Ota Kei | Zendy; Kinjo Rei | Zendy

AI Assistant Blog Pricing

Home ZAIA Blog

Premium

A Neutral and Aromatic Boron‐Rich Inorganic Benzene

Author(s) -

Ota Kei,

Kinjo Rei

Publication year - 2020

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.201915790

Subject(s) - cycloaddition , benzene , reactivity (psychology) , acetylene , boron , derivative (finance) , chemistry , ring (chemistry) , aromaticity , absorption (acoustics) , single crystal , photochemistry , organic chemistry , medicinal chemistry , computational chemistry , molecule , materials science , crystallography , catalysis , medicine , alternative medicine , pathology , financial economics , economics , composite material

A neutral 1,4‐diaza‐2,3,5,6‐tetraborinine derivative ( 3 ) featuring a 6π ring system has been synthesized and structurally characterized. The prospective aromatic nature of 3 was assessed by single‐crystal X‐ray analysis, NMR, and UV/Vis absorption spectroscopy as well as computational studies. Furthermore, preliminary reactivity investigations showed that 3 does not only react with diphenyl acetylene but also readily captures CO 2 in a [4+2] cycloaddition under ambient conditions.

This content is not available in your region!

Continue researching here.

Having issues? You can contact us here

Accelerating Research