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Controlled‐Atmosphere Flame Fusion Single‐Crystal Growth of Non‐Noble fcc, hcp, and bcc Metals Using Copper, Cobalt, and Iron
Author(s) -
Schuett Fabian M.,
Esau Derek,
Varvaris K. Liam,
Gelman Shelly,
Björk Jonas,
Rosen Johanna,
Jerkiewicz Gregory,
Jacob Timo
Publication year - 2020
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.201915389
Subject(s) - single crystal , noble metal , materials science , electrocatalyst , copper , fusion , crystallography , crystal (programming language) , cobalt , nanotechnology , electrochemistry , metal , metallurgy , chemistry , electrode , linguistics , philosophy , programming language , computer science
The growth of noble‐metal single crystals via the flame fusion method was developed in the 1980s. Since then, there have been no major advancements to the technique until the recent development of the controlled‐atmosphere flame fusion (CAFF) method to grow non‐noble Ni single crystals. Herein, we demonstrate the generality of this method with the first preparation of fcc Cu as well as the first hcp and bcc single crystals of Co and Fe, respectively. The high quality of the single crystals was verified using scanning electron microscopy and Laue X‐ray backscattering. Based on Wulff constructions, the equilibrium shapes of the single‐crystal particles were studied, confirming the symmetry of the fcc, hcp, and bcc single‐crystal lattices. The low cost of the CAFF method makes all kinds of high‐quality non‐noble single crystals independent of their lattice accessible for use in electrocatalysis, electrochemistry, surface science, and materials science.