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Dual Metal Active Sites in an Ir 1 /FeO x Single‐Atom Catalyst: A Redox Mechanism for the Water‐Gas Shift Reaction
Author(s) -
Liang JinXia,
Lin Jian,
Liu Jingyue,
Wang Xiaodong,
Zhang Tao,
Li Jun
Publication year - 2020
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.201914867
Subject(s) - chemistry , catalysis , water gas shift reaction , redox , formate , associative substitution , reaction mechanism , atom (system on chip) , adsorption , photochemistry , metal , vacancy defect , active site , inorganic chemistry , crystallography , biochemistry , organic chemistry , computer science , embedded system
Herein, we report a theoretical and experimental study of the water‐gas shift (WGS) reaction on Ir 1 /FeO x single‐atom catalysts. Water dissociates to OH* on the Ir 1 single atom and H* on the first‐neighbour O atom bonded with a Fe site. The adsorbed CO on Ir 1 reacts with another adjacent O atom to produce CO 2 , yielding an oxygen vacancy (O vac ). Then, the formation of H 2 becomes feasible due to migration of H from adsorbed OH* toward Ir 1 and its subsequent reaction with another H*. The interaction of Ir 1 and the second‐neighbouring Fe species demonstrates a new WGS pathway featured by electron transfer at the active site from Fe 3+ −O⋅⋅⋅Ir 2+ −O vac to Fe 2+ −O vac ⋅⋅⋅Ir 3+ −O with the involvement of O vac . The redox mechanism for WGS reaction through a dual metal active site (DMAS) is different from the conventional associative mechanism with the formation of formate or carboxyl intermediates. The proposed new reaction mechanism is corroborated by the experimental results with Ir 1 /FeO x for sequential production of CO 2 and H 2 .