Single‐Crystal X‐Ray Diffraction Study of Pressure and Temperature‐Induced Spin Trapping in a Bistable Iron(II) Hofmann Framework | Zendy

Turner Gemma F. | Zendy; Campbell Fallyn | Zendy; Moggach Stephen A. | Zendy; Parsons Simon | Zendy; Goeta Andrés E. | Zendy; Muñoz M. Carmen | Zendy; Real José A. | Zendy

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Single‐Crystal X‐Ray Diffraction Study of Pressure and Temperature‐Induced Spin Trapping in a Bistable Iron(II) Hofmann Framework

Author(s) -

Turner Gemma F.,

Campbell Fallyn,

Moggach Stephen A.,

Parsons Simon,

Goeta Andrés E.,

Muñoz M. Carmen,

Real José A.

Publication year - 2020

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.201914360

Subject(s) - bistability , trapping , diffraction , materials science , condensed matter physics , spin (aerodynamics) , chemistry , crystallography , thermodynamics , physics , optics , optoelectronics , ecology , biology

High‐pressure single‐crystal X‐ray diffraction has been used to trap both the low‐spin (LS) and high‐spin (HS) states of the iron(II) Hofmann spin crossover framework, [Fe II (pdm)(H 2 O)[Ag(CN) 2 ] 2 ⋅H 2 O, under identical experimental conditions, allowing the structural changes arising from the spin‐transition to be deconvoluted from previously reported thermal effects.

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