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Single‐Crystal X‐Ray Diffraction Study of Pressure and Temperature‐Induced Spin Trapping in a Bistable Iron(II) Hofmann Framework
Author(s) -
Turner Gemma F.,
Campbell Fallyn,
Moggach Stephen A.,
Parsons Simon,
Goeta Andrés E.,
Muñoz M. Carmen,
Real José A.
Publication year - 2020
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.201914360
Subject(s) - spin crossover , diffraction , bistability , spin transition , chemistry , crystallography , spin (aerodynamics) , trapping , x ray crystallography , single crystal , crystal (programming language) , spin states , materials science , condensed matter physics , thermodynamics , inorganic chemistry , physics , optics , ecology , programming language , optoelectronics , biology , computer science
High‐pressure single‐crystal X‐ray diffraction has been used to trap both the low‐spin (LS) and high‐spin (HS) states of the iron(II) Hofmann spin crossover framework, [Fe II (pdm)(H 2 O)[Ag(CN) 2 ] 2 ⋅H 2 O, under identical experimental conditions, allowing the structural changes arising from the spin‐transition to be deconvoluted from previously reported thermal effects.