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Photoinduced Multiple Effects to Enhance Uranium Extraction from Natural Seawater by Black Phosphorus Nanosheets
Author(s) -
Yuan Yihui,
Niu Biye,
Yu Qiuhan,
Guo Xin,
Guo Zhanhu,
Wen Jun,
Liu Tao,
Zhang Haiquan,
Wang Ning
Publication year - 2020
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.201913644
Subject(s) - photothermal therapy , uranium , adsorption , seawater , extraction (chemistry) , photocatalysis , chemical engineering , phosphorus , oxygen , materials science , nuclear chemistry , chemistry , nanotechnology , organic chemistry , catalysis , oceanography , geology , engineering , metallurgy
Based on the photoinduced photothermal, photoelectric, and photocatalytic effects of black phosphorus (BP) nanosheets, a BP‐PAO fiber with enhanced uranium extraction capacity and high antibiofouling activity is fabricated by compositing BP nanosheets into polyacrylamidoxime (PAO). The photothermal effect increases the coordination interaction between UO 2 2+ and the functional amidoxime group, and the photoelectric effect produces the surface positive electric field that exhibits electrostatic attraction to the negative [UO 2 (CO 3 ) 3 ] 4− , which all increase the capacity for uranium adsorption. The photocatalytic effect endows the adsorbent with high antibiofouling activity by producing biotoxic reactive oxygen species. Owing to these three photoinduced effects, the photoinduced BP‐PAO fiber shows a high uranium adsorption capacity of 11.76 mg g −1 , which is 1.50 times of the PAO fiber, in bacteria‐containing natural seawater.