Vapor‐Phase Linker Exchange of the Metal–Organic Framework ZIF‐8: A Solvent‐Free Approach to Post‐synthetic Modification | Zendy

Marreiros João | Zendy; Van Dommelen Lenz | Zendy; Fleury Guillaume | Zendy; OliveiraSilva Rodrigo | Zendy; Stassin Timothée | Zendy; Iacomi Paul | Zendy; Furukawa Shuhei | Zendy; Sakellariou Dimitrios | Zendy; Llewellyn Philip L. | Zendy; Roeffaers Maarten | Zendy; Ameloot Rob | Zendy

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Vapor‐Phase Linker Exchange of the Metal–Organic Framework ZIF‐8: A Solvent‐Free Approach to Post‐synthetic Modification

Author(s) -

Marreiros João,

Van Dommelen Lenz,

Fleury Guillaume,

OliveiraSilva Rodrigo,

Stassin Timothée,

Iacomi Paul,

Furukawa Shuhei,

Sakellariou Dimitrios,

Llewellyn Philip L.,

Roeffaers Maarten,

Ameloot Rob

Publication year - 2019

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.201912088

Subject(s) - linker , zeolitic imidazolate framework , metal organic framework , chemistry , solvent , phase (matter) , imidazolate , combinatorial chemistry , organic chemistry , adsorption , computer science , operating system

Zeolitic imidazolate frameworks (ZIFs) are a sub‐class of metal–organic frameworks (MOFs). Although generally stable, ZIFs can undergo post‐synthetic linker exchange (PSLE) in solution under mild conditions. Herein, we present a novel, solvent‐free approach to post‐synthetic linker exchange through exposure to linker vapor.

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