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Lattice Distortion in Hollow Multi‐Shelled Structures for Efficient Visible‐Light CO 2 Reduction with a SnS 2 /SnO 2 Junction
Author(s) -
You Feifei,
Wan Jiawei,
Qi Jian,
Mao Dan,
Yang Nailiang,
Zhang Qinghua,
Gu Lin,
Wang Dan
Publication year - 2020
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.201912069
Subject(s) - materials science , lattice (music) , visible spectrum , nanomaterials , crystal structure , nanostructure , nanotechnology , optoelectronics , template , catalysis , distortion (music) , selectivity , nanoscopic scale , chemistry , crystallography , physics , amplifier , biochemistry , cmos , acoustics
Precise control of the micro‐/nanostructures of nanomaterials, such as hollow multi‐shelled structures (HoMSs), has shown its great advantages in various applications. Now, the crystal structure of building blocks of HoMSs are controlled by introducing the lattice distortion in HoMSs, for the first time. The lattice distortion located at the nanoscale interface of SnS 2 /SnO 2 can provide additional active sites, which not only provide the catalytic activity under visible light but also improve the separation of photoexcited electron–hole pairs. Combined with the efficient light utilization, the natural advantage of HoMSs, a record catalytic activity was achieved in solid–gas system for CO 2 reduction, with an excellent stability and 100 % CO selectivity without using any sensitizers or noble metals.