Arene‐Free Ruthenium(II/IV)‐Catalyzed Bifurcated Arylation for Oxidative C−H/C−H Functionalizations | Zendy

Rogge Torben | Zendy; Ackermann Lutz | Zendy

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Arene‐Free Ruthenium(II/IV)‐Catalyzed Bifurcated Arylation for Oxidative C−H/C−H Functionalizations

Author(s) -

Rogge Torben,

Ackermann Lutz

Publication year - 2019

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.201909457

Subject(s) - ruthenium , reactivity (psychology) , catalysis , chemistry , selectivity , ligand (biochemistry) , combinatorial chemistry , oxidative phosphorylation , stereochemistry , medicinal chemistry , organic chemistry , receptor , biochemistry , medicine , alternative medicine , pathology

Experimental and computational studies provide detailed insight into the selectivity‐ and reactivity‐controlling factors in bifurcated ruthenium‐catalyzed direct C−H arylations and dehydrogenative C−H/C−H functionalizations. Thorough investigations revealed the importance of arene‐ligand‐free complexes for the formation of biscyclometalated intermediates within a ruthenium(II/IV/II) mechanistic manifold.

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