Synthesis of A Pincer‐Ir V  Complex with A Base‐Free Alumanyl Ligand and Its Application toward the Dehydrogenation of Alkanes | Zendy

Morisako Shogo | Zendy; Watanabe Seiya | Zendy; Ikemoto Satoru | Zendy; Muratsugu Satoshi | Zendy; Tada Mizuki | Zendy; Yamashita Makoto | Zendy

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Synthesis of A Pincer‐Ir V Complex with A Base‐Free Alumanyl Ligand and Its Application toward the Dehydrogenation of Alkanes

Author(s) -

Morisako Shogo,

Watanabe Seiya,

Ikemoto Satoru,

Muratsugu Satoshi,

Tada Mizuki,

Yamashita Makoto

Publication year - 2019

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.201909009

Subject(s) - pincer movement , pincer ligand , dehydrogenation , cyclooctane , ligand (biochemistry) , chemistry , lewis acids and bases , iridium , infrared spectroscopy , catalysis , xanes , free base , crystallography , medicinal chemistry , photochemistry , spectroscopy , organic chemistry , biochemistry , physics , receptor , quantum mechanics , salt (chemistry)

A pincer‐iridium complex bearing a Lewis‐base‐free X‐type alumanyl ligand has been synthesized. X‐ray diffraction, NMR and IR spectroscopy, as well as XANES analysis confirmed its tetrahydrido‐Ir V structure and Lewis acidity at the Al center as supported by DFT calculations. The resulting complex was applied as a catalyst for the transfer dehydrogenation of cyclooctane.

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