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Cover Picture: Stepwise Reduction of Azapentabenzocorannulene (Angew. Chem. Int. Ed. 35/2019)
Author(s) -
Zhou Zheng,
Wei Zheng,
Tokimaru Yuki,
Ito Shingo,
Nozaki Kyoko,
Petrukhina Marina A.
Publication year - 2019
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Reports
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.201908297
Subject(s) - alkali metal , reduction (mathematics) , cover (algebra) , ionic bonding , int , sodium , caesium , chemistry , nanotechnology , combinatorial chemistry , materials science , inorganic chemistry , organic chemistry , computer science , ion , engineering , mathematics , mechanical engineering , geometry , operating system
Reduced forms of N‐containing buckybowls with an umbrella shape were successfully isolated and characterized for the first time. In their Communication on page 12107 ff., S. Ito, K. Nozaki, M. A. Petrukhina, and co‐workers describe how their synthesis was accomplished through the controlled chemical reduction of azapentabenzocorannulene with two alkali metals of different ionic sizes and binding abilities, namely sodium and cesium.

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