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Molecular Design Strategy for Ordered Mesoporous Stoichiometric Metal Oxide
Author(s) -
Wang Changyao,
Wan Xiaoyue,
Duan Linlin,
Zeng Peiyuan,
Liu Liangliang,
Guo Dingyi,
Xia Yuan,
Elzatahry Ahmed A.,
Xia Yongyao,
Li Wei,
Zhao Dongyuan
Publication year - 2019
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.201907748
Subject(s) - stoichiometry , mesoporous material , crystallization , materials science , oxide , nanocrystal , chemical engineering , nanotechnology , cationic polymerization , chemistry , polymer chemistry , catalysis , organic chemistry , metallurgy , engineering
Abstract A molecular design strategy is used to construct ordered mesoporous Ti 3+ ‐doped Li 4 Ti 5 O 12 nanocrystal frameworks (OM‐Ti 3+ ‐Li 4 Ti 5 O 12 ) by the stoichiometric cationic coordination assembly process. Ti 4+ /Li + ‐citrate chelate is designed as a new molecular precursor, in which the citrate can not only stoichiometrically coordinate Ti 4+ with Li + homogeneously at the atomic scale, but also interact strongly with the PEO segments in the Pluronic F127. These features make the co‐assembly and crystallization process more controllable, thus benefiting for the formation of the ordered mesostructures. The resultant OM‐Ti 3+ ‐Li 4 Ti 5 O 12 shows excellent rate (143 mAh g −1 at 30 C) and cycling performances (<0.005 % fading per cycle). This work could open a facile avenue to constructing stoichiometric ordered mesoporous oxides or minerals with highly crystalline frameworks.