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Bis(1,3‐dithiol‐2‐ylidene)‐Substituted Subtriazachlorin: A Subphthalocyanine Analogue with Redox Properties
Author(s) -
Wang Yemei,
Mori Shigeki,
Furuta Hiroyuki,
Shimizu Soji
Publication year - 2019
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.201905331
Subject(s) - dithiol , tetrathiafulvalene , moiety , chemistry , redox , molecule , photochemistry , medicinal chemistry , polymer chemistry , stereochemistry , organic chemistry
Bis(1,3‐dithiol‐2‐ylidene)‐substituted subtriazachlorin was formed because of an unusual reaction of a 1,3‐dithiole‐2‐one‐fused subphthalocyanine in a triethylphosphite‐mediated tetrathiafulvalene synthesis. In this novel molecule, the bis(1,3‐dithiol‐2‐ylidene)ethane moiety and subtriazachlorin structure are fused, resulting in an electron‐donating ability and broad absorption in the near‐infrared region.