Premium
[Am(C 5 Me 4 H) 3 ]: An Organometallic Americium Complex
Author(s) -
Goodwin Conrad A. P.,
Su Jing,
AlbrechtSchmitt Thomas E.,
Blake Anastasia V.,
Batista Enrique R.,
Daly Scott R.,
Dehnen Stefanie,
Evans William J.,
Gaunt Andrew J.,
Kozimor Stosh A.,
Lichtenberger Niels,
Scott Brian L.,
Yang Ping
Publication year - 2019
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.201905225
Subject(s) - density functional theory , americium , spectroscopy , group 2 organometallic chemistry , crystallography , yield (engineering) , nuclear magnetic resonance spectroscopy , organometallic chemistry , ab initio , computational chemistry , ab initio quantum chemistry methods , chemistry , materials science , crystal structure , actinide , molecule , inorganic chemistry , stereochemistry , physics , organic chemistry , quantum mechanics , metallurgy
We report the small‐scale synthesis, isolated yield, single‐crystal X‐ray structure, 1 H NMR solution spectroscopy /solid‐state UV/Vis‐nIR spectroscopy, and density functional theory (DFT)/ab initio wave function theory calculations on an Am 3+ organometallic complex, [Am(C 5 Me 4 H) 3 ] ( 1 ). This constitutes the first quantitative data on Am−C bonding in a molecular species.