Nickel‐Catalyzed Arylboration of Alkenylarenes: Synthesis of Boron‐Substituted Quaternary Carbons and Regiodivergent Reactions | Zendy

Chen LiangAn | Zendy; Lear Alan R. | Zendy; Gao Pin | Zendy; Brown M. Kevin | Zendy

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Nickel‐Catalyzed Arylboration of Alkenylarenes: Synthesis of Boron‐Substituted Quaternary Carbons and Regiodivergent Reactions

Author(s) -

Chen LiangAn,

Lear Alan R.,

Gao Pin,

Brown M. Kevin

Publication year - 2019

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.201904861

Subject(s) - boron , nickel , catalysis , solvent , chemistry , scope (computer science) , combinatorial chemistry , organic chemistry , computer science , programming language

A method for the construction of boron‐substituted quaternary carbons or diarylquaternary carbons by arylboration of highly substituted alkenylarenes is presented. A wide range of alkenes and arylbromides can participate in this reaction thus allowing for a diverse assortment of products to be prepared. In addition, a solvent dependent regiodivergent arylboration of 1,2‐disubstituted alkenylarenes is presented, thus greatly increasing the scope of products that can be accessed.

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