Premium
Cover Picture: Selective Manganese‐Catalyzed Oxidation of Hydrosilanes to Silanols under Neutral Reaction Conditions (Angew. Chem. Int. Ed. 19/2019)
Author(s) -
Wang Kaikai,
Zhou Jimei,
Jiang Yuting,
Zhang Miaomiao,
Wang Chao,
Xue Dong,
Tang Weijun,
Sun Huamin,
Xiao Jianliang,
Li Chaoqun
Publication year - 2019
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Reports
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.201903074
Subject(s) - manganese , catalysis , chemistry , ligand (biochemistry) , metal , redox , noble metal , combinatorial chemistry , polymer chemistry , inorganic chemistry , organic chemistry , biochemistry , receptor
A manganese‐catalyzed oxidation of organosilanes with H 2 O 2 is described by J. L. Xiao, C. Q. Li et al. in their Communication on page 6380 ff. Silanols can be obtained by oxidation of hydrosilanes with various oxidants under noble‐metal catalysis. However, the methods developed to date generally suffer from the formation of byproducts. A manganese catalyst with an electron‐rich ligand was now employed in a simple, benign, and efficient process for the oxidation of various hydrosilanes and dihydrosilanes to silanols and silanediols without waste byproduct generation.