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Back Cover: General Cyclopropane Assembly by Enantioselective Transfer of a Redox‐Active Carbene to Aliphatic Olefins (Angew. Chem. Int. Ed. 18/2019)
Author(s) -
MontesinosMagraner Marc,
Costantini Matteo,
RamírezContreras Rodrigo,
Muratore Michael E.,
Johansson Magnus J.,
Mendoza Abraham
Publication year - 2019
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.201903064
Subject(s) - cyclopropane , stereocenter , carbene , enantioselective synthesis , cover (algebra) , redox , chemistry , carbon chain , combinatorial chemistry , carbon fibers , stereochemistry , catalysis , materials science , organic chemistry , ring (chemistry) , mechanical engineering , engineering , composite number , composite material
The construction of a carbon stereocenter in a future “carbon city” is shown in which these moieties are assembled in a unified and programmable way. This approach is well‐established in conventional construction in which a few general tools can build unrelated structures. As shown by A. Mendoza et al. in their Communication on page 5930 ff., one strategy can serve the assembly of cyclopropane stereocenters with different functionality (colored atoms in the illustration).