Organoiodine‐Catalyzed Enantioselective Alkoxylation/Oxidative Rearrangement of Allylic Alcohols | Zendy

Zhang DongYang | Zendy; Zhang Ying | Zendy; Wu Hua | Zendy; Gong LiuZhu | Zendy

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Organoiodine‐Catalyzed Enantioselective Alkoxylation/Oxidative Rearrangement of Allylic Alcohols

Author(s) -

Zhang DongYang,

Zhang Ying,

Wu Hua,

Gong LiuZhu

Publication year - 2019

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.201903007

Subject(s) - enantioselective synthesis , allylic rearrangement , catalysis , chemistry , oxidative phosphorylation , brønsted–lowry acid–base theory , organic chemistry , iodine , biochemistry

An enantioselective catalytic alkoxylation/oxidative rearrangement of allylic alcohols has been established by using a Brønsted acid and chiral organoiodine. The presence of 20 mol % of an ( S )‐proline‐derived C 2 ‐symmetric chiral iodine led to enantioenriched α‐arylated β‐alkoxylated ketones in good yields and with high levels of enantioselectivity (84–94 % ee ).

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