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Radical Umpolung: Efficient Options for the Synthesis of 1,4‐Dicarbonyl Compounds
Author(s) -
Chen XiangYu,
Enders Dieter
Publication year - 2019
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.201902132
Subject(s) - umpolung , chemoselectivity , chemistry , combinatorial chemistry , catalysis , amine gas treating , organocatalysis , photoredox catalysis , organic chemistry , enantioselective synthesis , photocatalysis , nucleophile
Radical developments : Photochemical/secondary amine dual catalysis has proven to be an efficient strategy for radical umpolung reactions. Two new processes provide an elegant solution to a long‐standing chemoselectivity problem for the synthesis of 1,4‐dicarbonyl compounds.
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