Selective Manganese‐Catalyzed Oxidation of Hydrosilanes to Silanols under Neutral Reaction Conditions | Zendy

Wang Kaikai | Zendy; Zhou Jimei | Zendy; Jiang Yuting | Zendy; Zhang Miaomiao | Zendy; Wang Chao | Zendy; Xue Dong | Zendy; Tang Weijun | Zendy; Sun Huamin | Zendy; Xiao Jianliang | Zendy; Li Chaoqun | Zendy

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Selective Manganese‐Catalyzed Oxidation of Hydrosilanes to Silanols under Neutral Reaction Conditions

Author(s) -

Wang Kaikai,

Zhou Jimei,

Jiang Yuting,

Zhang Miaomiao,

Wang Chao,

Xue Dong,

Tang Weijun,

Sun Huamin,

Xiao Jianliang,

Li Chaoqun

Publication year - 2019

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.201900342

Subject(s) - manganese , chemistry , catalysis , steric effects , alkyl , aryl , reaction conditions , organic chemistry

The first manganese‐catalyzed oxidation of organosilanes to silanols with H 2 O 2 under neutral reaction conditions has been accomplished. A variety of organosilanes with alkyl, aryl, alknyl, and heterocyclic substituents were tolerated, as well as sterically hindered organosilanes. The oxidation appears to proceed by a concerted process involving a manganese hydroperoxide species. Featuring mild reaction conditions, fast oxidation, and no waste byproducts, the protocol allows a low‐cost, eco‐benign synthesis of both silanols and silanediols.

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