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Frontispiece: Entropy‐Driven Diastereoselectivity Improvement in the Paternò–Büchi Reaction of 1‐Naphthyl Aryl Ethenes with a Chiral Cyanobenzoate through Remote Alkylation
Author(s) -
Nagasaki Keisuke,
Inoue Yoshihisa,
Mori Tadashi
Publication year - 2018
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Reports
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.201881861
Subject(s) - aryl , alkylation , chemistry , entropy (arrow of time) , stereochemistry , organic chemistry , thermodynamics , catalysis , physics , alkyl
Photochemistry In their Communication on page 4880 ff., T. Mori et al. highlight the critical role of entropy in determining the diastereoselectivity of Paternò–Büchi reactions of 1‐naphthyl aryl ethenes with a chiral 4‐cyanobenzoate.