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Inside Back Cover: Puffing Up Energetic Metal–Organic Frameworks to Large Carbon Networks with Hierarchical Porosity and Atomically Dispersed Metal Sites (Angew. Chem. Int. Ed. 7/2019)
Author(s) -
Zhao Ruo,
Liang Zibin,
Gao Song,
Yang Ce,
Zhu Bingjun,
Zhao Junliang,
Qu Chong,
Zou Ruqiang,
Xu Qiang
Publication year - 2019
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Reports
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.201814367
Subject(s) - carbonization , carbon fibers , materials science , porosity , metal , cover (algebra) , transition metal , fabrication , metal organic framework , metal ions in aqueous solution , nanotechnology , chemical engineering , composite material , chemistry , metallurgy , composite number , catalysis , organic chemistry , adsorption , mechanical engineering , scanning electron microscope , medicine , alternative medicine , pathology , engineering
An energetic metal–organic framework (EMOF) with pre‐imbedded transition‐metal ions serves as a precursor for the fabrication of large carbon networks with hierarchical pores and atomically dispersed metal sites (ADMSs). In their Communication on page 1975 ff., Q. Xu, R. Zou, and co‐workers describe the high‐temperature carbonization of this material: the zinc‐based triazole‐rich nanoparticles puff up to form sub‐millimeter‐scale carbon networks, while the pre‐imbedded transition‐metal ions are transformed into active ADMSs.