Phosphine‐Stabilized Diiododiborenes: Isolable Diborenes with Six Labile Bonds | Zendy

Muessig Jonas H. | Zendy; Thaler Melanie | Zendy; Dewhurst Rian D. | Zendy; Paprocki Valerie | Zendy; Seufert Jens | Zendy; Mattock James D. | Zendy; Vargas Alfredo | Zendy; Braunschweig Holger | Zendy

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Phosphine‐Stabilized Diiododiborenes: Isolable Diborenes with Six Labile Bonds

Author(s) -

Muessig Jonas H.,

Thaler Melanie,

Dewhurst Rian D.,

Paprocki Valerie,

Seufert Jens,

Mattock James D.,

Vargas Alfredo,

Braunschweig Holger

Publication year - 2019

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.201814230

Subject(s) - lability , phosphine , halide , reactivity (psychology) , chemistry , cleavage (geology) , medicinal chemistry , bond cleavage , polymer chemistry , stereochemistry , photochemistry , organic chemistry , catalysis , materials science , medicine , alternative medicine , pathology , fracture (geology) , composite material

The lability of B=B, B−P, and B–halide bonds is combined in the syntheses of the first diiododiborenes. In a series of reactivity tests, these diiododiborenes undergo cleavage of all six of their central bonds in different ways, leading to products of B=B hydrogenation and dihalogenation as well as halide exchange.

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