Cover Picture: Dual Gold‐Catalyzed Cycloaromatization of Unconjugated ( E )‐Enediynes (Angew. Chem. Int. Ed. 7/2019) | Zendy

Zamani Farzad | Zendy; Babaahmadi Rasool | Zendy; Yates Brian F. | Zendy; Gardiner Michael G. | Zendy; Ariafard Alireza | Zendy; Pyne Stephen G. | Zendy; Hyland Christopher J. T. | Zendy

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Cover Picture: Dual Gold‐Catalyzed Cycloaromatization of Unconjugated ( E )‐Enediynes (Angew. Chem. Int. Ed. 7/2019)

Author(s) -

Zamani Farzad,

Babaahmadi Rasool,

Yates Brian F.,

Gardiner Michael G.,

Ariafard Alireza,

Pyne Stephen G.,

Hyland Christopher J. T.

Publication year - 2019

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Reports

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.201814227

Subject(s) - chemistry , catalysis , moiety , homogeneous , stereochemistry , combinatorial chemistry , organic chemistry , mathematics , combinatorics

Dual gold activation is an important catalytic mode in homogeneous catalysis. In their Communication on page 2114 ff., S. G. Pyne, C. J. T. Hyland, and co‐workers report that ( E )‐enediynes undergo a dual gold‐catalyzed cycloaromatization towards isoindolinones. They use electronic differentiation of triple bonds to direct the formation of a propiolic gold acetylide, represented as a gold‐coveting dragon, which then reacts with a π‐coordinated enyne moiety, illustrated by Rumpelstilzchen spinning his golden thread.

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