Premium
Atomically Dispersed Ruthenium Species Inside Metal–Organic Frameworks: Combining the High Activity of Atomic Sites and the Molecular Sieving Effect of MOFs
Author(s) -
Ji Shufang,
Chen Yuanjun,
Zhao Shu,
Chen Wenxing,
Shi Lijun,
Wang Yu,
Dong Juncai,
Li Zhi,
Li Fuwei,
Chen Chen,
Peng Qing,
Li Jun,
Wang Dingsheng,
Li Yadong
Publication year - 2019
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.201814182
Subject(s) - catalysis , ruthenium , alkyne , molecular sieve , nanotechnology , metal organic framework , metal , chemistry , heterogeneous catalysis , regioselectivity , materials science , chemical engineering , combinatorial chemistry , organic chemistry , adsorption , engineering
Incorporating atomically dispersed metal species into functionalized metal–organic frameworks (MOFs) can integrate their respective merits for catalysis. A cage‐controlled encapsulation and reduction strategy is used to fabricate single Ru atoms and triatomic Ru 3 clusters anchored on ZIF‐8 (Ru 1 @ZIF‐8, Ru 3 @ZIF‐8). The highly efficient and selective catalysis for semi‐hydrogenation of alkyne is observed. The excellent activity derives from high atom‐efficiency of atomically dispersed Ru active sites and hydrogen enrichment by the ZIF‐8 shell. Meanwhile, ZIF‐8 shell serves as a novel molecular sieve for olefins to achieve absolute regioselectivity of catalyzing terminal alkynes but not internal alkynes. Moreover, the size‐dependent performance between Ru 3 @ZIF‐8 and Ru 1 @ZIF‐8 is detected in experiment and understood by quantum‐chemical calculations, demonstrating a new and promising approach to optimize catalysts by controlling the number of atoms.