Inside Cover: Mechanism of the Water–Gas Shift Reaction Catalyzed by Efficient Ruthenium‐Based Catalysts: A Computational and Experimental Study (Angew. Chem. Int. Ed. 3/2019) | Zendy

Stepić Robert | Zendy; Wick Christian R. | Zendy; Strobel Vinzent | Zendy; Berger Daniel | Zendy; VučemilovićAlagić Nataša | Zendy; Haumann Marco | Zendy; Wasserscheid Peter | Zendy; Smith AnaSunčana | Zendy; Smith David M. | Zendy

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Inside Cover: Mechanism of the Water–Gas Shift Reaction Catalyzed by Efficient Ruthenium‐Based Catalysts: A Computational and Experimental Study (Angew. Chem. Int. Ed. 3/2019)

Author(s) -

Stepić Robert,

Wick Christian R.,

Strobel Vinzent,

Berger Daniel,

VučemilovićAlagić Nataša,

Haumann Marco,

Wasserscheid Peter,

Smith AnaSunčana,

Smith David M.

Publication year - 2019

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Reports

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.201813595

Subject(s) - water gas shift reaction , ruthenium , catalysis , chemistry , reaction mechanism , cover (algebra) , kinetic energy , photochemistry , organic chemistry , mechanical engineering , physics , quantum mechanics , engineering

The production of H 2 gas can be achieved at low temperatures using ruthenium‐based catalysts for the water–gas shift reaction (WGSR). Using a combined theoretical and experimental approach, D. M. Smith and co‐workers present in their Communication on page 741 ff. a new mechanism for the WGSR, involving anionic, Cl‐rich, Ru carbonyl complexes. The new understanding, which is supported by kinetic isotope effects, is a step towards large‐scale industrial production of H 2 at low temperatures.

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