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Direct Carbohydroxylation of Arylalkenes with Allylic Alcohols: Cooperative Catalysis of Copper, Silver, and a Brønsted Acid
Author(s) -
Ahmed Waqar,
Zhang Sheng,
Yu Xiaoqiang,
Feng Xiujuan,
Yamamoto Yoshinori,
Bao Ming
Publication year - 2019
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.201813148
Subject(s) - allylic rearrangement , catalysis , olefin fiber , surface modification , copper , brønsted–lowry acid–base theory , chemistry , organic chemistry , combinatorial chemistry
The cooperative catalysis of copper, silver, and Brønsted acid is presented as a new strategy for olefin functionalization. The catalytic direct carbohydroxylation of arylalkenes with allylic alcohols provided a straightforward and efficient approach for preparing 4,5‐unsaturated alcohols. Synthetically useful functional groups, such as Cl, Br, carbonyl, and chloromethyl, remained intact during the functionalization reaction.