Direct Carbohydroxylation of Arylalkenes with Allylic Alcohols: Cooperative Catalysis of Copper, Silver, and a Brønsted Acid | Zendy

Ahmed Waqar | Zendy; Zhang Sheng | Zendy; Yu Xiaoqiang | Zendy; Feng Xiujuan | Zendy; Yamamoto Yoshinori | Zendy; Bao Ming | Zendy

Premium

Direct Carbohydroxylation of Arylalkenes with Allylic Alcohols: Cooperative Catalysis of Copper, Silver, and a Brønsted Acid

Author(s) -

Ahmed Waqar,

Zhang Sheng,

Yu Xiaoqiang,

Feng Xiujuan,

Yamamoto Yoshinori,

Bao Ming

Publication year - 2019

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.201813148

Subject(s) - allylic rearrangement , catalysis , olefin fiber , surface modification , copper , brønsted–lowry acid–base theory , chemistry , organic chemistry , combinatorial chemistry

The cooperative catalysis of copper, silver, and Brønsted acid is presented as a new strategy for olefin functionalization. The catalytic direct carbohydroxylation of arylalkenes with allylic alcohols provided a straightforward and efficient approach for preparing 4,5‐unsaturated alcohols. Synthetically useful functional groups, such as Cl, Br, carbonyl, and chloromethyl, remained intact during the functionalization reaction.

This content is not available in your region!

Continue researching here.

Having issues? You can contact us here

Accelerating Research