Back Cover: Probing Hydrogen Bonding Interactions to Iron‐Oxido/Hydroxido Units by  57 Fe Nuclear Resonance Vibrational Spectroscopy (Angew. Chem. Int. Ed. 49/2018) | Zendy

Weitz Andrew C. | Zendy; Hill Ethan A. | Zendy; Oswald Victoria F. | Zendy; Bominaar Emile L. | Zendy; Borovik Andrew S. | Zendy; Hendrich Michael P. | Zendy; Guo Yisong | Zendy

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Back Cover: Probing Hydrogen Bonding Interactions to Iron‐Oxido/Hydroxido Units by 57 Fe Nuclear Resonance Vibrational Spectroscopy (Angew. Chem. Int. Ed. 49/2018)

Author(s) -

Weitz Andrew C.,

Hill Ethan A.,

Oswald Victoria F.,

Bominaar Emile L.,

Borovik Andrew S.,

Hendrich Michael P.,

Guo Yisong

Publication year - 2018

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.201812786

Subject(s) - hydrogen bond , chemistry , coordination sphere , hydrogen , resonance (particle physics) , reactivity (psychology) , substrate (aquarium) , spectroscopy , crystallography , cover (algebra) , atomic physics , molecule , physics , crystal structure , organic chemistry , medicine , mechanical engineering , alternative medicine , oceanography , pathology , quantum mechanics , engineering , geology

Hydrogen bond strength to iron(III)–oxido/hydroxido (Fe III –O/OH) units in nonheme iron complexes is revealed by Fe III –O/OH stretching vibrations detected with 57 Fe nuclear resonance vibrational spectroscopy (NRVS), as shown by Y. Guo et al. in their Communication on page 16010. The study provides a method for elucidating the influence of hydrogen bonds in the secondary coordination sphere on the stability of Fe III –O/OH. This feature may correlate with the reactivity of Fe IV =O in substrate oxidation.

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