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Inside Cover: Synthesis and Properties of a Highly Congested Tri(9‐anthryl)methyl Radical (Angew. Chem. Int. Ed. 50/2018)
Author(s) -
Nishiuchi Tomohiko,
Aibara Seito,
Kubo Takashi
Publication year - 2018
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Reports
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.201812504
Subject(s) - int , cover (algebra) , absorbance , redox , chemistry , radical ion , propeller , medicinal chemistry , organic chemistry , computer science , mechanical engineering , ion , chromatography , engineering , operating system , marine engineering
A propeller‐shaped highly congested mesityl‐substituted tri(9‐anthryl)methyl radical was synthesized by developing a method that overcomes the challenges posed by the bulky substituents. In their Communication on page 16516 ff., T. Nishiuchi, T. Kubo, and S. Aibara also report on the high persistency, wide‐range absorbance, good reversible redox properties, and dimerization behavior of this radical.