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Carbonylation of Alkyl Radicals Derived from Organosilicates through Visible‐Light Photoredox Catalysis
Author(s) -
Cartier Alex,
Levernier Etienne,
Corcé Vincent,
Fukuyama Takahide,
Dhimane AnneLise,
Ollivier Cyril,
Ryu Ilhyong,
Fensterbank Louis
Publication year - 2019
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.201811858
Subject(s) - carbonylation , radical , alkyl , carbon monoxide , chemistry , catalysis , photochemistry , photoredox catalysis , primary (astronomy) , organic chemistry , photocatalysis , physics , astronomy
Primary, secondary, and tertiary alkyl radicals formed by the photocatalyzed oxidation of organosilicates underwent efficient carbonylation with carbon monoxide (CO) to give a variety of unsymmetrical ketones. This study introduces the possibility of radical carbonylation under a photooxidative regime.