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Dehydrogenative Aromatization and Sulfonylation of Pyrrolidines: Orthogonal Reactivity in Photoredox Catalysis
Author(s) -
Muralirajan Krishnamoorthy,
Kancherla Rajesh,
Rueping Magnus
Publication year - 2018
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.201808427
Subject(s) - aromatization , reagent , catalysis , chemistry , reactivity (psychology) , photoredox catalysis , combinatorial chemistry , oxidative phosphorylation , organic chemistry , photochemistry , photocatalysis , medicine , biochemistry , alternative medicine , pathology
Abstract Oxidative dehydrogenative aromatization and selective sulfonylation reactions of N ‐heterocycles under visible‐light photoredox catalysis were established. The mild reaction conditions make this approach an appealing and versatile strategy to functionalize/oxidize pyrrolidines whereby arylsulfonyl chlorides were identified to be both catalyst regeneration and sulfonylation reagents.