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The H 2 S Dimer is Hydrogen‐Bonded: Direct Confirmation from Microwave Spectroscopy
Author(s) -
Das Arijit,
Mandal Pankaj K.,
Lovas Frank J.,
Medcraft Chris,
Walker Nicholas R.,
Arunan Elangannan
Publication year - 2018
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.201808162
Subject(s) - dimer , van der waals force , hydrogen bond , service (business) , hydrogen , computer science , chemistry , world wide web , molecule , organic chemistry , business , marketing
Ice and solid H 2 S look as different as pears and oranges, leading Pauling to conclude that H 2 O has hydrogen bonds and H 2 S has van der Waals interactions. Now it is shown that the H 2 S dimer, like the H 2 O dimer, is indeed hydrogen‐bonded.
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